https://www.performanceexhaust.com.au/Vic based, but pretty sure they do nationwide.
Nice guys, they're like 10 mins from my house and have a big arse warehouse for the parts.
As far as tube material, clamps, and all the other stuff, really depends on the intended use.
A 2 bolt flange is plenty for basically every join in a non-turbo car, and most of the cat onwards on a turbo car. (heat being the main issue)
Pipe material is more about personal preference and longevity, mild steel is cheap but not particularly pretty since it will rust (worth noting, you'll likely still get 15 years out of it before it rusts a hole through)
Stainless is more costly and comes in a few grades, from the basic "it wont rust but it's not shiny" to the "it's shiny enough to shave with and will stay that way"
both with last pretty much the life of the car, but are harder to work with, and yeah, costly to buy.
They were fine with talking over the finer details with me over the counter, so should be able to do the same via email.
So far as actually making the exhaust at home.
Unless you already own a pipe bender, and a MIG/TIG, or intend to do a few exhausts, it will generally be cheaper to have a shop do it for you, rather than buy the tools.